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![CAS:110529-22-1|(S)-(+)-2-[羟基(二苯基)甲基]-1-甲基吡咯烷](/images/icon1.jpg)
CAS:110529-22-1|(S)-(+)-2-[羟基(二苯基)甲基]-1-甲基吡咯烷
作者：德尔塔 日期：2022-03-04
二烷基锌不对称加成到羰基化合物的反应所用配体 Ligand employed in the enantioselective addition of dialkylzincs to carbonyls属性 产品名称 (S)-(+)-2-[羟基(二苯基)甲基]-1-甲基吡咯烷 产品名称 (S)-(+)-2-[Hydroxy(diphenyl)methyl]-1-methylpyrrolidine 别名 α,α-二苯基-N-甲基-L-脯氨醇 英文别名 (S)-alpha,alpha-Diphenyl-1-methylpyrrolidine-2-methanol (S)-α,α-Diphenyl-N-methyl-2-pyrrolidinemethanol α,α-Diphenyl-N-methyl-L-prolinol (S)-(+)-Diphenyl(1-methylpyrrolidin-2-yl)methanol CAS编号 110529-22-1 分子式 C18H21NO 分子量 267.37 PubChem CID 87571133
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CAS:4378-13-6|O-叔丁基-L-苏氨酸
作者：德尔塔 日期：2022-03-04
属性 产品名称 O-叔丁基-L-苏氨酸 产品名称 O-tert-Butyl-L-threonine 别名 H-Thr(tBu)-OH; (2S,3S)-2-Amino-3-(tert-butoxy)butyric acid; H-Thr(tBu)-OH 英文别名 H-Thr(tBu)-OH; (2S,3S)-2-Amino-3-(tert-butoxy)butyric acid; H-Thr(tBu)-OH CAS编号 4378-13-6 分子式 C8H17NO3 分子量 175.23 PubChem CID 6951357 MDL号 MFCD00037766 Beilstein 2206127
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CAS:69257-04-1|N-苄基氯化辛可宁丁
作者：德尔塔 日期：2022-03-04
属性 产品名称 N-苄基氯化辛可宁丁 产品名称 N-Benzylcinchonidinium Chloride 别名 BCDC 英文别名 (8S,9R)-()-N-Benzylcinchonidinium chloride CAS编号 69257-04-1 分子式 C26H29ClN2O 分子量 420.98 PubChem CID 10938717 MDL号 MFCD00082422 Beilstein 5421832 Reaxys-RN
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CAS:69221-14-3|N-苄基氯化辛可宁[手性相转移催化剂]
作者：德尔塔 日期：2022-03-04
Phase-transfer catalyst involved in: Enantioselective alkylation of malonic diester with alkyl halides Hydrolysis of enol esters Asymmetric 6π electrocyclization for synthesis of functionalized indolines Asymmetric Michael addition Alkylation of monosubstituted indolinones with alkylhalides Asymmetric destruction and kinetic resolution of 1-benzylated Reissert compounds Phase-transfer catalyst involved in: Enantioselective alkylation of malonic diester with alkyl halides Hydrolysis of enol esters Asymmetric 6π electrocyclization for synthesis of functionalized indolines Asymmetric Michael addition Alkylation of monosubstituted indolinones with alkylhalides Asymmetric destruction and kinetic resolution of 1-benzylated Reissert compounds属性 产品名称 N-苄基氯化辛可宁[手性相转移催化剂] 产品名称 N-Benzylcinchoninium Chloride [Chiral Phase-Transfer Catalyst] 别名 BCNC 英文别名 BCNC CAS编号 69221-14-3
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CAS:887919-35-9|二氯双[二叔丁基-(4-二甲基氨基苯基)膦]钯(II)
作者：德尔塔 日期：2022-03-04
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) is a highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling with aryl halides including 5- and 6-membered heteroaryl chlorides.A highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling Application Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) is a highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling with aryl halides including 5- and 6-membered heteroaryl chlorides. A highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling Product class M-P, Homogeneous Catalysts, Monodentate Ligands, Phosphorus Ligands - Achiral Reaction type Cross Coupling Reactions with Arenes, Suzuki-Miyaura Coupling Reaction Chemical properties Chemical formula C32H56N2Cl2P2Pd Empirical formula [Pd(amphos)2Cl2] Molecular weight 708.08 Metal Pd Theoretical metal content 15 Physical state powder Color yellow Applications & references Synthesis of the pyrazolopyridinone-based p38 mitogen-activated protein kinase inhibitor including a Suzuki coupling reaction. p38 MAP kinases are intercellular serine/threonine kinases which certainly regulate the production and action of several pro-inflammatory mediators. They are also involved in disease states such as rheumatoid arthritis, Crohn’s diseases and psoriasis. Reference: Org. Proc. Res. Dev. 2011, 15, 31. (DOI: 10.1021/op100205s)属性 产品名称
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CAS:112022-81-8|(S)-(-)-2-甲基-CBS-噁唑硼烷
作者：德尔塔 日期：2022-03-04
用于不对称还原和不对称合成的CBS催化剂CBS（Corey-Bakshi-Shibata）恶唑硼烷催化剂已被用于前手性酮的不对称还原。其它应用包括对映选择性合成α-羟基酸、α- 氨基酸、C2对称二茂铁基二醇和炔丙醇。 Usually used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C2-symmetrical ferrocenyl diols, and propargyl alcohols.属性 产品名称 (S)-(-)-2-甲基-CBS-噁唑硼烷 产品名称 (S)-(-)-2-Methyl-CBS-oxazaborolidine 别名 (S)-2-甲基-CBS-氧杂硼啶；(S)-5,5-联苯-2-甲基-3,4-丙醇-1,3,2-恶唑硼烷；(S)-3,3-二苯基-1-甲基四氢-1H,3H-吡咯并[1,2-c][1,3,2]恶唑硼烷； (S)-Me-CBS催化剂 英文别名 (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine;(S)-3,3-Diphenyl-1-methyltetrahydro-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole;(S)-Me-CBS Catalyst CAS编号 112022-81-8 分子式 C18H20BNO
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CAS:84025-81-0|(R)-2-(甲氧甲基)吡咯烷
作者：德尔塔 日期：2022-03-04
属性 产品名称 (R)-2-(甲氧甲基)吡咯烷 产品名称 (R)-2-(Methoxymethyl)pyrrolidine 别名 (R)-(-)-2-(甲氧基甲基)吡咯烷 英文别名 O-Methyl-D-prolinol (R)-(-)-2-(Methoxymethyl)pyrrolidine CAS编号 84025-81-0 分子式 C6H13NO 分子量 115.17 PubChem CID 671216 MDL号 MFCD00066219 Beilstein 4229755
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CAS:63126-47-6|(S)-2-(甲氧甲基)吡咯烷
作者：德尔塔 日期：2022-03-04
手性助剂，用于不对称合成炔丙醇 和 4-硝基环己酮， 以及用于不对称 Michael 加成反应生成烯酮。 Chiral auxiliary for asymmetric synthesis of propargy alcohols1 and 4-nitrocyclohexanones, and for asymmetric Michael additions to enones.属性 产品名称 (S)-2-(甲氧甲基)吡咯烷 产品名称 (S)-2-(Methoxymethyl)pyrrolidine 别名 O-甲基-L-脯氨醇 英文别名 O-Methyl-L-prolinol, SMP (S)-(+)-2-(Methoxymethyl)pyrrolidine CAS编号 63126-47-6 分子式 C6H13NO 分子量 115.17 PubChem CID 671217 MDL号 MFCD00010
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CAS:106681-15-6|二乙酰基[(S)-(-)-2,2'-双(二-P-苯基磷酰)-1,1'联萘]钌
作者：德尔塔 日期：2022-03-04
Takasago Ligands and Complexes for Asymmetric Reactions Takasago Ligands and Complexes for Asymmetric Reactions属性 产品名称 二乙酰基[(S)-(-)-2,2'-双(二-P-苯基磷酰)-1,1'联萘]钌 产品名称 (S)-Ru(OAc)2(T-BINAP) 别名 Diacetato[(S)-()-2,2′-bis(di-p-tolylphosphino)-1,1′-binaphthyl]ruthenium(II) 英文别名 Diacetato[(S)-()-2,2′-bis(di-p-tolylphosphino)-1,1′-binaphthyl]ruthenium(II) CAS编号 106681-15-6 分子式 C52H46O4P2Ru 分子量 897.94 PubChem CID 11007467 MDL号 MFCD09753021
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CAS:261948-85-0|二乙酸[(S)-(-)-2,2'-双(二苯基膦)-1,1'-联萘基]钌(II)
作者：德尔塔 日期：2022-03-04
应用 用于催化： zaragozic acid D的合成以及zaragozic acid A和C的形式合成,用于不对称反应的Takasago配体和配合物。 通过钯催化的，有机硅烷醇基交叉偶联反应和路易斯碱催化的对映选择性烯丙基化反应，对映选择性合成螺环C-芳基吡喃葡萄糖苷（+） -阜孢霉素D 2-甲酰基-1-亚甲基-1,2,3,4-四氢异喹啉的不对称氢化 （硝基）（苯基）丙烯的不对称还原 通过氢化不对称合成手性d-内酯 双（二苯基膦酰基）丁二烯的不对称氢化 Product class M-P, Homogeneous Catalysts, M-O, Acetate Ligands, Phosphorus Ligands - Chiral Reaction type Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation Chemical properties Chemical formula C48H38O4P2Ru Empirical formula Ru[(S)-BINAP](OAc)2 Molecular weight 841.84 Metal Ru Theoretical metal content 12 Physical state powder Color orange Applications & references Catalytic asymmetric hydrogenation of functionalized acrylic acid derivatives for the synthesis of pharmaceutically active substances. Reference: US2005 0070714 Asymmetric hydrogenation of diketenes. Reference: J. Org. Chem. 1995, 60, 357 (DOI: 10.1021/jo00107a014) Asymmetric hydrogenation of five-membred α,β-unsaturated carbonyl compounds. Reference: J. Org. Chem. 1995, 60, 357 (DOI: 10.1021/jo00107a014) Hydroxyl directed hydrogenation in the total synthesis of zaragozic acids. Reference: Chem. Eur. J. 2011, 17, 3335 (DOI: 10.1002/chem.201003399) Asymmetric hydrogenation toward the general asymmetric synthesis of isoquinoline alkaloids, e.g. morphine. Reference: Tetrah. 2006, 62, 5448 (DOI: 10.1016/j.tet.2006.03.055)属性
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CAS:130004-33-0|[(S)-(-)-2,2'-双(二苯基膦)-1,1'-联萘基](对伞花烃)氯化钌(II)氯化物
作者：德尔塔 日期：2022-03-04
Product class M-P, Homogeneous Catalysts, M-C, Arene/Aryl Ligands, Phosphorus Ligands - Chiral Reaction type Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation Chemical properties Chemical formula C54H46Cl2P2Ru Empirical formula [RuCl(p-cymene)(S)-BINAP)]Cl Molecular weight 928.88 Metal Ru Theoretical metal content 11 Physical state powder Color red orange Applications & references Synthesis of (R)- or (S)-4-halo-3-hydroxybuyrate ester by asymmetric hydrogenation of 4-halo-3-oxobutanoate ester; this reaction can be applied in the Producteion of L-carnitine. Reference: EP2386536 Enantioselective hydrogenation of functionalized ketones. Reference: EP0366390 Asymmetric hydrogenation of halogenated acetophenones to enantiomerically pure halogenated phenyl ethanol derivatives. Reference: Cat. Lett. 1996, 41, 111 (DOI: 10.1007/BF00811721) Highly enantioselective catalytic hydrogenation of methyl-N-tertbutyl-3-oxoglutarate as a key step in the total synthesis of rovastatin. Reference: Tetrah. Lett. 2008, 49, 4836 (DOI: 10.1016/j.tetlet.2008.06.018) Enantioselective hydrogenation of 4-(hydroxymethyl)furan-2(5H)-one derivatives. Reference: J. Mol. Cat. A: Chem. 2006, 259, 103 (DOI: 10.1016/j.molcata.2006.05.066)属性 产品名称 [(S)-(-)-2,2'-双(二苯基膦)-1,1'-联萘基](对伞花烃)氯化钌(II)氯化物
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CAS:488809-34-3|三(μ-氯)双[(S)-(-)-5,5'-双(二苯基膦)-4,4'-联-1,3-苯并二恶茂]二氯化二钌二甲基铵盐
作者：德尔塔 日期：2022-03-04
属性 产品名称 三(μ-氯)双[(S)-(-)-5,5'-双(二苯基膦)-4,4'-联-1,3-苯并二恶茂]二氯化二钌二甲基铵盐 产品名称 (S)-[(RuCl(SEGPHOS®;))₂(μ-Cl)₃][NH₂Me₂] 别名 Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(−)-5，5′-bis(diphenylphosphino)-4，4′-bi-1，3-benzodioxole]diruthenate(II) 英文别名 Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(−)-5，5′-bis(diphenylphosphino)-4，4′-bi-1，3-benzodioxole]diruthenate(II) CAS编号 488809-34-3 分子式 (CH3)2NH2+[C76H56Cl5O8P4Ru2]− 分子量 1646.64 PubChem CID 71310555 MDL号
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CAS:309735-86-2|三(μ-氯)双[(S)-(-)-2,2'-双(二对甲苯基膦)-1,1'-联萘]二氯化二钌二甲基铵盐
作者：德尔塔 日期：2022-03-04
属性 产品名称 三(μ-氯)双[(S)-(-)-2,2'-双(二对甲苯基膦)-1,1'-联萘]二氯化二钌二甲基铵盐 产品名称 (S)-[(RuCl(T-BINAP))₂(μ-Cl)₃[NH₂Me₂] 别名 二甲铵二氯三(μ-氯)双[(S)-(-)-2,2′-双(二-对甲苯基膦)-1,1′-联萘基]二钌酸盐(II) 英文别名 (S)-[(RuCl (T-BINAP))2(μ-Cl)3[NH2Me2];[NH2Me2][(RuCl((S)-tolbinap))2(μ-Cl)3];Dimethylammonium Dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II CAS编号 309735-86-2 分子式 (CH3)2NH2+[C96H80Cl5P4Ru2]- 分子量 1783.05 PubChem CID 49871361 MDL号
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CAS:134524-84-8|[(S)-2,2'-双(二苯基磷)-1,1'-联萘]二氯化钌(II)
作者：德尔塔 日期：2022-03-04
product description：1. Enantios elective catalyst for the as ymmetric hydrog enation of a, B-unsaturated olefins .2. Efficient catalyst for the asymmetric reduction of carbonyl groups, such as B-ketoes ters .属性 产品名称 [(S)-2,2'-双(二苯基磷)-1,1'-联萘]二氯化钌(II) 产品名称 [(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride 别名 (S)-BINAP 二氯化钌络合物；(S)-[1,1′-联萘]-2,2′-二基双[二苯膦]钌络合物 英文别名 Dichloro[(S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II);(1S)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine-κP]]dichloro-ruthenium;(S)-BINAP dichlororuthenium complex;(S)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine]ruthenium co CAS编号 134524-84-8 分子式 C44H32Cl2P2Ru 分子量
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CAS:53448-09-2|D-亮氨醇
作者：德尔塔 日期：2022-03-04
N-Protection and transformation of OH group. Selective O-derivatization. N-Protection and transformation of OH group. Selective O-derivatization.属性 产品名称 D-亮氨醇 产品名称 D-(-)-Leucinol 别名 (R)-(-)-亮氨醇;D-(-)-亮氨醇 英文别名 (R)-(-)-Leucinol;D-(-)-Leucinol;(R)-2-Amino-4-methyl-1-pentanol CAS编号 53448-09-2 分子式 C6H15NO 分子量 117.19 PubChem CID 10772 MDL号 MFCD00004734
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