【产品介绍】：

应用 用于催化： zaragozic acid D的合成以及zaragozic acid A和C的形式合成,用于不对称反应的Takasago配体和配合物。 通过钯催化的，有机硅烷醇基交叉偶联反应和路易斯碱催化的对映选择性烯丙基化反应，对映选择性合成螺环C-芳基吡喃葡萄糖苷（+） -阜孢霉素D 2-甲酰基-1-亚甲基-1,2,3,4-四氢异喹啉的不对称氢化 （硝基）（苯基）丙烯的不对称还原 通过氢化不对称合成手性d-内酯 双（二苯基膦酰基）丁二烯的不对称氢化 Product class M-P, Homogeneous Catalysts, M-O, Acetate Ligands, Phosphorus Ligands - Chiral Reaction type Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation Chemical properties Chemical formula C48H38O4P2Ru Empirical formula Ru[(S)-BINAP](OAc)2 Molecular weight 841.84 Metal Ru Theoretical metal content 12 Physical state powder Color orange Applications & references Catalytic asymmetric hydrogenation of functionalized acrylic acid derivatives for the synthesis of pharmaceutically active substances. Reference: US2005 0070714 Asymmetric hydrogenation of diketenes. Reference: J. Org. Chem. 1995, 60, 357 (DOI: 10.1021/jo00107a014) Asymmetric hydrogenation of five-membred α,β-unsaturated carbonyl compounds. Reference: J. Org. Chem. 1995, 60, 357 (DOI: 10.1021/jo00107a014) Hydroxyl directed hydrogenation in the total synthesis of zaragozic acids. Reference: Chem. Eur. J. 2011, 17, 3335 (DOI: 10.1002/chem.201003399) Asymmetric hydrogenation toward the general asymmetric synthesis of isoquinoline alkaloids, e.g. morphine. Reference: Tetrah. 2006, 62, 5448 (DOI: 10.1016/j.tet.2006.03.055)属性 产品名称 二乙酸[(S)-(-)-2,2'-双(二苯基膦)-1,1'-联萘基]钌(II) 产品名称 Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 别名 Chiralyst Ru843;Ru(OAc)2[(S)-binap] 英文别名 Chiralyst Ru843;Ru(OAc)2[(S)-binap] CAS编号 261948-85-0 分子式 C48H38O4P2Ru 分子量 841.83 PubChem CID 11083409 MDL号 MFCD09753020 INCHI 1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-32H;2*1H3,(H,3,4);/q;;;+2/p-2 InChi Key NMLZYEWNUCRSRJ-UHFFFAOYSA-L 法律信息 Product of Umicore 敏感性 对光敏感、对空气敏感 运输条件 常规运输