CAS:325146-81-4|二乙酸根[(R)-(+)-2,2'-二(二苯基膦基)-1,1'-联萘基]钌(II)
【产品介绍】:
Product Description 1.Catalyst system that exhibits very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. Product class M-P, Homogeneous Catalysts, M-O, Acetate Ligands, Phosphorus Ligands - Chiral Reaction type Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation Chemical properties Chemical formula C48H38O4P2Ru Empirical formula Ru[(R)-BINAP](OAc)2 Molecular weight 841.84 Metal Ru Theoretical metal content 12 Physical state powder Color tan Applications & references Asymmetric hydrogenation of ß-ketoester for the enantioselective synthesis of (R)-d-lactones. Reference: WO2001 057014 Enantioselective synthesis of levetiracetam including asymmetric hydrogenation of (Z)-2-(2-oxopyrrolidin-1-yl)but-2-enamide. Reference: WO2001 064637 Synthesis of (S)-fluoromethyldihydro-furan-2-one for the manufacture of pyrido[2,1-a]isoquinoline derivatives which are useful for treatment or prophylaxis of diseases. Reference: WO2006 125728 Asymmetric hydrogenation of five-membred α,β-unsaturated carbonyl compounds. Reference: J. Org. Chem. 1995, 60, 357 (DOI: 10.1021/jo00107a014)