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CAS号:1864-94-4|苯甲酸酯

发布时间:2022-04-14     作者:德尔塔   分享到:

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中文别名 苯甲酸酯 英文别名 Phenyl formate CAS号 1864-94-4 SMILES c1ccc(cc1)OC=O Inchi InChI=1S/C7H6O2/c8-6-9-7-4-2-1-3-5-7/h1-6H InchiKey GEOWCLRLLWTHDN-UHFFFAOYSA-N 分子式 Formula C7H6O2 分子量 Molecular Weight 122 闪点 FP 52.6±17.2 °C 熔点 Melting point 87℃ 沸点 Boiling point 165.2±13.0 °C at 760 mmHg Polarizability极化度 13.1±0.5 10-24cm3 密度 Density 1.1±0.1 g/cm3 蒸汽压 Vapor Pressure 2.5±0.3 mmHg at 25°C 溶解度Solubility 性状 储藏条件 Storage conditions storage at -4℃ (1-2weeks), longer storage period at -20℃ (1-2years) 实验注意事项:1.实验前需戴好防护眼镜,穿戴防护服和口罩,佩戴手套,避免与皮肤接触。2.实验过程中如遇到有毒或者刺激性物质及有害物质产生,必要时实验操作需要手套箱内完成以免对实验人员造成伤害3.实验后产生的废弃物需分类存储,并交于专业生物废气物处理公司处理,以免造成环境污染Experimental considerations: 1. Wear protective glasses, protective clothing and masks, gloves, and avoid contact with the skin during the experiment. 2. The waste generated after the experiment needs to be stored separately, and handed over to a professional biological waste gas treatment company to avoid environmental pollution. 产品说明 苯甲酸酯仅用于科学研究实验使用,不得用于其他用途 IntroductionPhenyl formate Only used for scientific research experiments, not for other purposes Application1 Application2 Application3 警示图 危险性 warning 危险性警示 Not available 安全声明 H303吞入可能有害+H313皮肤接触可能有害+H333吸入可能对身体有害 安全防护 P264处理后彻底清洗+P280戴防护手套/穿防护服/戴防护眼罩/戴防护面具+P305如果进入眼睛+P351用水小心冲洗几分钟+P338取出隐形眼镜(如果有)并且易于操作,继续冲洗+P337如果眼睛刺激持续+P313获得医疗建议/护理 备注 实验过程中防止吸入、食入,做好安全防护 Peter Fr?hlich, Kristin Albert and Martin Bertau.Formate dehydrogenase - a biocatalyst with novel applications in organic chemistry,Org. Biomol. Chem., 2011, 9, 7941.[DOI: 10.1039c1ob06064c] Parameters of the conformational equilibrium in phenyl formate,Bulletin of the Academy of Sciences of the USSR, Division of chemical science[DOI: 10.1007BF00962742] Carbonylation with Formates,Science of SynthesisKonishi, Hideyuki; Manabe, Kei, Synlett 2014, 25, 1971-1986.Formic Acid Derivatives as Practical Carbon Monoxide Surrogates for Metal-Catalyzed Carbonylation Reactions,Synlett[DOI: 10.1055s-0033-1339136] Chavan, Sujit P.; K., Adithyaraj; Bhanage, Bhalchandra M..In situ Generation and Utilization of CO: An Efficient Route towards N-Substituted Saccharin via Carbonylative Cyclization of 2-Iodosulfonamides,Synlett 2017, 28, 2000-2003[DOI: 10.1055s-0036-1588422] Peng, Jin-Bao; Qi, Xinxin; Wu, Xiao-Feng.Recent Achievements in Carbonylation Reactions: A Personal Account,Synlett 2017, 28, 175-194[DOI: 10.1055s-0036-1588351]